High density monolayer of diisocyanide on gold surface as a platform of supported Rh-catalyst for selective 1,4-hydrogenation of a,b-unsaturated carbonyl compounds†

نویسندگان

  • S. Jagtap
  • Y. Kaji
  • A. Fukuoka
  • K. Hara
چکیده

Title High density monolayer of diisocyanide on gold surface as a platform of supported Rh-catalyst for selective 1,4hydrogenation of α,β-unsaturated carbonyl compounds Author(s) Jagtap, Sachin; Kaji, Yoshinori; Fukuoka, Atsushi; Hara, Kenji Citation Chemical Communications, 50: 5046-5048 Issue Date 2014-04 DOI Doc URL http://hdl.handle.net/2115/55274 Right Type article Additional Information File Information c3cc48181f.pdf

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High density monolayer of diisocyanide on gold surface as a platform of supported Rh-catalyst for selective 1,4-hydrogenation of α,β-unsaturated carbonyl compounds.

A high density monolayer of diisocyanide on gold surface was utilized as a platform of supported Rh catalyst for selective 1,4-hydrogenation of α,β-unsaturated carbonyl compounds. The catalyst exhibited high turnover numbers in a range of 50 000 to 150 000 per Rh atom and showed steady catalyst performance over six recycle usages.

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تاریخ انتشار 2014